W. G. Pritchard Lab Seminar: 4-5 PM, 116 McAllister Building **Tuesday March 19, 2002** Dynamics of Hot Spots in Solid Fuel Combustion Bernard J. Matkowsky Department of Engineering Sciences and Applied Mathematics Northwestern University Abstract: We consider the gasless combustion model of the Self-Propagating High-Temperature Synthesis (SHS) process in which combustion waves are employed to synthesize desired materials. Specifically, we consider the combustion of a solid sample in which combustion occurs on the surface of a cylinder of radius R. We consider solution behavior as R is increased. This parameter is important for technological applications, as it is often desirable to synthesize large samples of the desired product. For fixed value of the Zeldovich number, if R is sufficiently small, slowly propagating planar pulsating flames are the only modes observed. As R is increased transitions to more complex modes of combustion occur, including (i) spin modes in which one or several symmetrically spaced hot spots rotate around the cylinder as the flame propagates along the cylindrical axis, thus following a helical path, (ii) counterpropagating (CP) modes, in which spots propagate in opposite angular directions around the cylinder, (iii) alternating spin CP modes (ASCP), where rotation of the spot is interrupted by periodic events in which a new spot is spontaneously created ahead of the rotating spot. The new spot splits into daughter spots, one of which collides with the original spot leading to their eventual mutual annihilation, while the other continues to spin, (iv) modulated spin waves consisting of one or two symmetric rotating spots which exhibit a periodic modulation in speed and temperature (v) asymmetric spin waves in which two spots of unequal strength rotate together as a bound state, (vi) modulated asymmetric spin waves in which the two asymmetric spots oscillate in a periodic manner as they rotate, (vii) asymmetric ASCP modes in which a slowly varying bound state of two spots rotates while the leading spot, and subsequently the trailing spot, exhibits episodes of ASCP behavior, and finally (viii) 3-headed spins in which three spots rotate in a nonuniform fashion, including quasiperiodic and chaotic motion.