%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% W. G. Pritchard Lab Seminar: 11:15 AM - 12:15 PM, 216 McAllister Bldg **Monday October 31, 2005** Domain dependence of piezoelectricity in domain-engineered crystals Wenwu Cao Department of Mathematics Penn State University Abstract: Experimental studies indicate that the effective properties of multi- domain ferroelectric crystals strongly depend on the domain size. Using a 2-D time-dependent Landau-Ginzburg model incorporating elastic, electrostatic and electromechanical interactions, we have simulated the piezoelectric properties of domain engineered ferroelectric single crystals. Three different microstructures with different sized domains are analyzed. We have found that the field-induced phase transitions are highly sensitive to the direction of the field relative to the crystal axes, and to the domain size. Since the proximity to the transition enhances piezoelectric behavior, the effective piezoelectric constants of smaller domain is significantly enhanced. Our model may also explain domain size dependence in other single crystal systems. %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%